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Chromium as a metallic element was first discovered two
hundred years ago, in 1797. But the history of chromium really
began several decades before this.
In 1761, Johann Gottlob Lehmann visited the Beresof Mines on
the Eastern slopes of the Ural Mountains where he obtained samples
of an orange-red mineral which he termed Siberian red lead.
On his return to St. Petersburg in 1766, he analysed this mineral
and discovered that it contained lead "mineralised with
a selenitic spar and iron particles".
In fact, the mineral was crocoite, a lead chromate (PbCrO4).
In 1770, Peter Simon Pallas also visited the Beresof Mines
and observed "a very remarkable red lead mineral which
has never been found in any other mine. When pulverised, it
gives a handsome yellow guhr which could be used in miniature
painting...".
In spite of its rarity and the difficulty with which it was
obtained from the Beresof Mines (the transport to Western Europe
often taking two years), the use of Siberian red lead as a paint
pigment was quickly appreciated and it was mined both as a collector's
item as well as for the paint industry - a bright yellow made
from crocoite fast became the fashionable colour for the carriages
of the nobility in both France and England.
In 1797, Nicolas-Louis Vauquelin, professor of chemistry and
assaying, at the School of Mines in Paris, received some samples
of crocoite ore. His subsequent analysis revealed a new metallic
element, which he called chromium after the Greek word khrôma,
meaning colour.
After further research he detected trace elements of chromium
in precious gems - giving the characteristic red colour of rubies
and the distinctive green of emeralds, serpentine, and chrome
mica.
In 1798, Lowitz and Klaproth independently discovered chromium
in a sample of a heavy black rock found further north from the
Beresof Mines and in 1799 Tassaert identified chromium in the
same mineral from a small deposit in the Var region of South-Eastern
France.
This mineral he determined as the chromium-iron spinel now known
as chromite (FeOCr2O3).
The chromite ore deposits discovered in the Ural Mountains greatly
increased the supplies of chromium to the growing paint industry
and even resulted in a chromium chemicals factory being set
up in Manchester, England around 1808. In 1827, Isaac Tyson
identifed deposits of chromite ore on the Maryland-Pennsylvania
border and the USA became the monopoly supplier for a number
of years.
But high-grade chromite deposits were found near Bursa in Turkey
in 1848 and with the exhaustion of the Maryland deposits around
1860, it was Turkey that then became the main source of supply.
This continued for many years until the mining of chromium ore
started in India and Southern Africa around 1906. And although
paint pigments remained the main application for many years,
chromium was finding other uses: Kochlin introduced the use
of potassium dichromate as a mordant in the dyeing industry
in 1820.
The use of chromium salts in leather tanning was adopted commercially
in 1884. While chromite was first used as a refractory in France
in 1879, its real use started in Britain in 1886.
The first patent for the use of chromium in steel was granted
in 1865 - but the large-scale use of chromium had to wait until
chromium metal could be produced by the alumino-thermic route,
developed in the early 1900s and when the electric arc furnace
could smelt chromite into the master alloy, ferrochromium.
Whilst metal finishing brought shine and brilliance to add
to the catalogue of chromium colours, a true vocation came with
the invention of stainless steels, for chromium is the ingredient
that makes steel stainless.
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